| 引用本文: | 李银奎,刘清芝,黄钐,等.聚对苯撑及其衍生物的合成、表征和电性能.[J].国防科技大学学报,1996,18(3):49-53.[点击复制] |
| Li Yinkui,Liu Qingzhi,Huang Shan,et al.The Study of Synthesis，Characteristics and Conductivity of Poly-p-phenylene and Its Derivatives[J].Journal of National University of Defense Technology,1996,18(3):49-53[点击复制] |
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| 聚对苯撑及其衍生物的合成、表征和电性能 |
| 李银奎1, 刘清芝1, 黄钐1, 孙巍1, 龙永福1, 刘玉明2, 孙乐民2 |
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(1.国防科技大学 材料工程与应用化学系 湖南 长沙 4100073;2.国防科技大学 图书馆 湖南 长沙 410073)
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| 摘要: |
| 从溴苯合成出了聚对苯撑，从对苯二酚合成出了几种聚对苯撑的衍生物：聚(2，5-二甲氧基)对苯撑，聚(2，5-二乙氧基)对苯撑和聚(2，5-二丁氧基)对苯撑。用IR 表征了中间体和聚合物的结构，测定了聚合物的电导率和伏安特性曲线，并讨论了实验条件对产率的影响。 |
| 关键词: 聚对苯撑，聚 (2，5-二甲氧基〕对苯撑，聚 (2，5-二乙氧基〕对苯撑，聚 (2，5-二丁氧基)对苯撑 |
| DOI： |
| 投稿日期：1996-02-05 |
| 基金项目: |
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| The Study of Synthesis，Characteristics and Conductivity of Poly-p-phenylene and Its Derivatives |
| Li Yinkui1, Liu Qingzhi1, Huang Shan1, Sun Wei1, Loug Yongfu1, Liu Yuming2, Sun Lemin2 |
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(1.Department of Materials Engineering and Applied Chemistry，NUDT，Changsha，410073;2.Library of NUDT, Changsha，410073)
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| Abstract: |
| With tetrapyridine nickel dinitrile (TPNDN) as Catalyst，the poly-p-phenylene (ppph) is synthesized from bromobenzene. The derivatives of ppph，poly (2，5-dimethoxy)-p-phenylene，poly (2，5-diethoxy)-p-phenylene and poly (2，5-dibutoxy)-p-phenylene are synthesized from hydroquinone by using FeCl3 as catalyst. IR spectra of these polymers are presented and conductivity and current versus voltage (I-V) characteristics are determined. |
| Keywords: poly-p-phenylene,poly (2,5-dimethoxy)-p-phenylene,poly (2,5-diethoxy)-p-phenylene,poly (2,5-dibutoxy)-p-phenylene |
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