| 引用本文: | 杨小红,陈蓉,范真祥,等.超声合成β-烷氧基萘.[J].国防科技大学学报,2002,24(6):31-33.[点击复制] |
| YANG Xiaohong,CHEN Rong,FAN Zhenxiang,et al.Supersonic Synthesis of β-alkoxynaphthalenel[J].Journal of National University of Defense Technology,2002,24(6):31-33[点击复制] |
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| 超声合成β-烷氧基萘 |
| 杨小红1, 陈蓉1, 范真祥2, 王璟2 |
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(1.湖南师范大学医学院，湖南 长沙 410006;2.国防科技大学 航天与材料工程学院，湖南 长沙 410073)
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| 摘要: |
| 以β-萘酚和H(CH2)nBr (n=4、7、9)为原料,甲醇钠(CH3ONa)和甲醇为溶剂，在N2气保护下，用超声催化合成β-烷氧基萘，反应5h，收率可达94%。反应的适宜条件为：β-萘酚 和H(CH2)nBr摩尔比为1∶1，甲醇钠的浓度为2.0mol/L(溶剂CH3OH)，超声频率33±2kHz。 |
| 关键词: 超声波 β-萘酚 β-烷氧基萘 合成 |
| DOI： |
| 投稿日期：2002-06-10 |
| 基金项目: |
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| Supersonic Synthesis of β-alkoxynaphthalenel |
| YANG Xiaohong1, CHEN Rong1, FAN Zhenxiang2, WANG Jing2 |
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(1.Medial College,Hunan Normal University，Changsha 410006,China;2.College of Aerospace and Materials Engineering, National Univ. of Defense Technology, Changsha 410073, China)
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| Abstract: |
| β-alkoxynaphthalenel was prepared from β-naphthol and H(CH2)n Br under nitrogen in the supersonic waves. Sodium methoxyide and methanol was solvent.The yield was 94%. The reaction conditions: molar ratio of β-naphthol/H(CH2)n Br was 1,condensation of sodium methoxide was 2.0 mol/L,supersonic ratio was 33±2kHz,reaction time was 5h. |
| Keywords: supersonic waves β-naphthol β-alkoxynaphthalenel synthesis |
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