聚碳硅烷先驱体交联后热处理对陶瓷转化的影响
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国家部委重点资助项目


Effects of Heat-treatment Following Crosslinkingof Polycarbosilane on Ceramic Conversation
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    摘要:

    将聚碳硅烷交联产物在裂解前,先在200~400℃进行不同温度下的热处理,研究其对陶瓷转化过程的影响。结果表明,经400℃/2h热处理后,其裂解产物的陶瓷产率达到73.9%;裂解产物结构的主要缺陷为气孔,而未经热处理样品裂解产物结构的主要缺陷为裂纹。如果用该结构的陶瓷为基体,可以减少纤维损伤。

    Abstract:

    The crosslinked products of polycarbosilane were heated between 200-400℃ before pyrolysis in order to investigate their effects on conversation of ceramic. It was shown that 73.9% ceramic yield was raised when heated two hours at 400℃.The dominating defects in structure of its product pyrolysed were pores,not cracks in structure of that without heat-treatment.The damage of fiber could be decreased significantly if such ceramic were used as base.

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陈曼华,陈朝辉.聚碳硅烷先驱体交联后热处理对陶瓷转化的影响[J].国防科技大学学报,2003,25(2):38-40.
CHEN Manhua, CHEN Zhaohui. Effects of Heat-treatment Following Crosslinkingof Polycarbosilane on Ceramic Conversation[J]. Journal of National University of Defense Technology,2003,25(2):38-40.

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  • 收稿日期:2002-10-21
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  • 在线发布日期: 2013-06-14
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