树脂浸渍裂解对气相硅反应渗透C/SiC的影响
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国家部委预研基金资助项目(41312011002)


Effects of Impregnation and Pyrolysis of Resin on the C/SiCComposites Fabricated by Reactive Infiltration of Gaseous Silicon
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    摘要:

    粘胶基碳纤维毡经过CVD工艺进行沉积碳增密处理后,采用酚醛树脂浸渍—裂解对C/C素坯的密度进行调节,通过气相硅渗透反应工艺制备了C/SiC复合材料。研究了树脂浸渍—裂解对C/C素坯密度和气孔率的影响规律,分析了树脂裂解碳对C/SiC显微形貌和力学性能的影响。结果表明:随着树脂浸渍—裂解循环次数的增加,素坯密度增加,孔隙率降低;裂解碳含量为27wt%时,C/SiC复合材料的强度和模量达到最大,分别为231MPa和209GPa。通过控制裂解碳含量,可以实现对C/SiC复合材料力学性能和微观结构的裁剪。

    Abstract:

    C/SiC composites were manufactured by the process of reactive infiltration of gaseous silicon with carbon felt reinforced carbon green, which is made from viscose rayon-based carbon felt perform treated with CVD carbon and phenolic resin pyrolysis carbon. Effects of re-impregnation and pyrolysis cycles of resin on the density and porosities of green and the micrograph and mechanical properties of C/SiC were studied. The result indicates that with the increase of re-impregnation cycles and the density of green, the porosities of green declines. The bending strength and modulus of C/SiC reach the maximal figures, respectively 231MPa and 209GPa when the pyrolysis carbon content of preform is set to 27wt%. The mechanical and microstructure properties of C/SiC can be tailored by controlling the pyrolysis carbon volume in the green.

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周浩,张长瑞,曹英斌,等.树脂浸渍裂解对气相硅反应渗透C/SiC的影响[J].国防科技大学学报,2006,28(3):33-36.
ZHOU Hao, ZHANG Changrui, CAO Yingbin, et al. Effects of Impregnation and Pyrolysis of Resin on the C/SiCComposites Fabricated by Reactive Infiltration of Gaseous Silicon[J]. Journal of National University of Defense Technology,2006,28(3):33-36.

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  • 收稿日期:2006-02-16
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  • 在线发布日期: 2013-03-14
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