聚硅氧烷先驱体转化制备2D Cf/Si-O-C材料
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国家部委基金资助项目(51488030105ZS9504)


Study of 2D Cf/Si-O-C Fabricated via Polysiloxane Pyrolysis
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    摘要:

    以二维碳纤维布和廉价的聚硅氧烷为原料,采用先驱体转化工艺制备2D Cf/Si-O-C材料,对其力学性能进行了考察,并与以聚碳硅烷为先驱体制备的2D Cf/SiC材料在价格和性能方面进行了对比。实验表明,2D Cf/Si-O-C材料力学性能较2D Cf/SiC材料有所下降,但成本大大降低。2D Cf/Si-O-C材料弯曲强度达到157.9 MPa,断裂韧性达到8.4MPa?m1/2,剪切强度达到23.4MPa,并且在1400℃下能较好保持材料的力学性能。

    Abstract:

    Carbon fiber cloth reinforced silicon oxycarbide (2D Cf/Si-O-C) composites were fabricated with cheap polysiloxane (PSO) and divinylbenzene (DVB) as precursors and carbon fiber cloth as reinforcements. The mechanical properties of 2D Cf/Si-O-C composites with polysiloxane as precursors were investigated and the difference of properties and cost between them and 2D Cf/SiC composites were also studied in the paper. The results show that the mechanical properties of 2D Cf/Si-O-C are decreased and the cost of them reduced greatly. The flexural strength, fracture toughness and shear strength reach 157.9MPa, 8.4MPa?m1/2 and 23.4MPa respectively. Such mechanical properties can be reserved up to 1400℃.

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刘静宇,陈朝辉,简科.聚硅氧烷先驱体转化制备2D Cf/Si-O-C材料[J].国防科技大学学报,2006,28(5):30-34.
LIU Jingyu, CHEN Zhaohui, JIAN Ke. Study of 2D Cf/Si-O-C Fabricated via Polysiloxane Pyrolysis[J]. Journal of National University of Defense Technology,2006,28(5):30-34.

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  • 收稿日期:2006-05-10
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  • 在线发布日期: 2013-03-14
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