In multi-station electronic reconnaissance system, TDOA (Time Difference Of Arrival) of the pulse signal received by two stations can be used for signal sorting and positioning. A novel method for joint sorting and location based on TDOA and multiparameter of multi-station was proposed to deal with the problem of being unable to sort the signals with very few pulses caused by weak correlation between pulse information of complex signals in order to obtain final sorting and location results, the pulses of all stations were presorted by the presented method with TDOA window information and the presorting results were integrated according to targets’ positions. Simulation results show that the proposed method is applicable and effective, which can implement the pulse signal sorting and positioning with very few pulses and even a single pulse sorting and positioning.