| 引用本文: | 方美宇,周家茵,周世光,等.四-(对-甲氧苯基)卟啉氧钒(Ⅳ)配合物的合成与表征.[J].国防科技大学学报,1992,14(3):107-111.[点击复制] |
| Fang Meiyu,Zhou Jiayin,Zhou Shiguang,et al.Synthesis and Characterization of Tetra-(P-methoxyphenyl)Porphyrinoxovanadium(Ⅳ)Macrocyclic Coordination Compound[J].Journal of National University of Defense Technology,1992,14(3):107-111[点击复制] |
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| 四-(对-甲氧苯基)卟啉氧钒(Ⅳ)配合物的合成与表征 |
| 方美宇1, 周家茵1, 周世光1, 綦尤训1, 卓宗亮2 |
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(1.材料科学与应用化学系;2.华东师范大学分析测试中心)
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| 摘要: |
| 在丙酸溶剂中合成了一种新的大环配合物四-(对-甲氧苯基)卟啉氧钒(Ⅳ)[tetra-(P-me-thoxyphenyl)porphyrinoxovana dium(Ⅳ)，T(P-OCH3)PPVO]，进行了元素分析和差热-热重分析，测定了其紫外-可见光谱、红外光谱和电子顺磁共振谱，确定了配合物的组成、对称性及立体结构。 |
| 关键词: 络合物化学，配位化合物，氧钒配合物 |
| DOI： |
| 投稿日期：1991-04-30 |
| 基金项目:1991年第四届亚洲化学大会(4ACC)交流论文 |
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| Synthesis and Characterization of Tetra-(P-methoxyphenyl)Porphyrinoxovanadium(Ⅳ)Macrocyclic Coordination Compound |
| Fang Meiyu1, Zhou Jiayin1, Zhou Shiguang1, Qi Youxun1, Zhuo Zongliang2 |
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(1.Department of Material Science and Applied Chemistry;2.East China Normal University，Testing Center)
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| Abstract: |
| A new macrocyclic coordination compound，tetra-(P-methoxyphenyl)porphyrinoxovanadium(Ⅳ)[T(P-OCH3)PPVO] was synthesized in propionic acid solvent. The composition of T(P-OCH3)PPVO was determined as C48H36N4O4VO? 4H2O by elemental analysis and EDTA complexometric methods. The UV-visible spectra showed that the formation of the title coordination compound，and the ligand and coordination compound are macrocyclic. Disappearance of the N-H stretching vibration peak in IR spectra of the T(P-OCH3)PPVO revealed the introduction of the central ion VO2+ into the porphyrin ring. The TG-DTA-DTG results demonstrated that the different dewatering mechanism of the ligand and complex are four molecules of H2O broken away in one step (the ligand)，and two by two stepwise of the four H2O molecules(the complex). Sixteen distinct lines attributed to interaction of nuclear spin of vanadium(Ⅳ)with the 3dI electron appeared clearly in the ESR spectra of title macrocyclic compound，indicating that its structural model is a distorted octahedron belonging to C4v point group. |
| Keywords: coordination chemistry,vanadyl coordination compound,macrocylic coordination compound |
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