| 引用本文: | 周勇强,周家茵,周世光,等.Cu(Ⅱ)大环希夫碱配合物的合成与表征.[J].国防科技大学学报,1992,14(3):112-116.[点击复制] |
| Zhou Yongqiang,Zhou Jiayin,Zhou Shiguang,et al.Synthesis and Characterization of Copper(Ⅱ) Complex with Macrocyclic Schiff Base[J].Journal of National University of Defense Technology,1992,14(3):112-116[点击复制] |
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| Cu(Ⅱ)大环希夫碱配合物的合成与表征 |
| 周勇强, 周家茵, 周世光, 綦尤训 |
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(材料科学与应用化学系)
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| 摘要: |
| 以邻苯二甲醛和邻苯二胺为原料，三水合硝酸铜为模板剂，用模板反应在无水乙醇中制备了一种新的固体配合物[CuL]（NO3)2? 6H2O。通过元素分析、磁化率及摩尔电导测定、红外光谱和电子光谱分析、热重-差热分析等，确定了配合物的组成、立体结构与对称性，并对其电致变色机理进行了初步的探讨。 |
| 关键词: 配位化学，配合化合物，氧钒配合物，大环希夫碱配合物，Cu(Ⅱ)配合物模板反应，电致变色 |
| DOI： |
| 投稿日期：1991-04-30 |
| 基金项目: |
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| Synthesis and Characterization of Copper(Ⅱ) Complex with Macrocyclic Schiff Base |
| Zhou Yongqiang, Zhou Jiayin, Zhou Shiguang, Qi Youxun |
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(Department of Material Science and Applied Chemistry)
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| Abstract: |
| A new solid complex [CuL]（NO3)2 ? 6H2O with the macrocyclic schiff base has been synthesized by
the template reaction of copper(Ⅱ)nitrate with O-phenylenediamine and O-phthalicaldehyde in absolute ethane medium. The characteristics of the products have been analyzed by elemental analysis, IR spectra, UV-visible spectra, molar conductance, magnetic susceptibility，differential thermal analysis (DTA) and thermogravimetry (TG) measurements. Based on these analyses, the composition, structure and symmetry of the complexes have been discussed, meanwhile, the properties and mechanism of electrochromism of the complex are preliminary investigated. |
| Keywords: coordination chemistry,coordination compound,vanadyl compounds,template reaction,copper (Ⅱ) complex,macrocyclic schiff base complex,electrochromism |
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