| 引用本文: | 王军,高四,王亦菲,等.纳米二氧化硅增强硬质聚氨酯泡沫塑料的制备.[J].国防科技大学学报,2004,26(4):86-89.[点击复制] |
| WANG Jun,GAO Si,WANG Yifei,et al.Preparation of Nano Silicon Dioxide Reinforced Rigid Polyurethane Foam[J].Journal of National University of Defense Technology,2004,26(4):86-89[点击复制] |
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| 纳米二氧化硅增强硬质聚氨酯泡沫塑料的制备 |
| 王军1, 高四1, 王亦菲1, 汪萍1, 王建华2, 刘永华2 |
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(1.国防科技大学 航天与材料工程学院，湖南 长沙 410073;2.中国工程物理研究院化工材料研究所，四川 绵阳 621900)
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| 摘要: |
| 采用功率超声，将纳米二氧化硅颗粒分散到多次甲基多苯基多异氰酸酯体系内，然后与聚醚多元醇聚合制得了纳米二氧化硅增强的硬质聚氨酯泡沫塑料。SEM分析表明，纳米二氧化硅均匀分散在聚氨酯泡沫中。在较低添加量时，纳米二氧化硅使压缩强度和冲击强度有一定提高，但会引起多次甲基多苯基多异氰酸酯粘度迅速增加，从而导致发泡反应困难，当添加量为7wt%时，压缩强度和冲击强度开始下降。 |
| 关键词: 聚氨酯泡沫塑料 纳米二氧化硅 力学性能 |
| DOI： |
| 投稿日期：2004-02-20 |
| 基金项目: |
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| Preparation of Nano Silicon Dioxide Reinforced Rigid Polyurethane Foam |
| WANG Jun1, GAO Si1, WANG Yifei1, WANG Ping1, WANG Jianhua2, LIU Yonghua2 |
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(1.College of Aerospace and Materials Engineering, National Univ.of Defense Technology, Changsha 410073,China;2.Institute of Chemical Materials，China Academy of Engineering Physics，Mianyang 621900，China)
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| Abstract: |
| By power ultrasonic, nano silicon dioxide particles were dispersed into polyaryl-polymethylene-isocryanate(PAPI)and rigid polyurethane foams reinforced by nano SiO2 were prepared by polymerization PAPI with polyether polyol. SEM was employed to observe the structures of SiO2 filled polyurethane foam and showed that nano SiO2 particles had been dispersed uniformly in foam. Results of mechanic test show that nano SiO2 particles in low loading fraction can increase the compressed strength and impact strength of the rigid polyurethane foam. But the addition of nano SiO2 conduces to the rapid accretion of viscosity of PAPI, which makes the foam reaction difficult to set in and the impact strength decreases with the addition of 7% nano SiO2. |
| Keywords: polyurethane foam nano silicon dioxide mechanical properties |
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