| 引用本文: | 门金凤,程海峰,陈朝辉,等.新型硫代双烯镍络合物合成及其对菁染料的光稳定作用.[J].国防科技大学学报,2008,30(5):29-33.[点击复制] |
| MEN Jinfeng,CHENG Haifeng,CHEN Zhaohui,et al.Synthesis of New Bis(1,2-diaryl-1,2-ethylenedithiolato) Nickel Complex and its Photostability to Cyanine Dye[J].Journal of National University of Defense Technology,2008,30(5):29-33[点击复制] |
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| 新型硫代双烯镍络合物合成及其对菁染料的光稳定作用 |
| 门金凤1,2, 程海峰1, 陈朝辉1, 楚增勇1, 郑文伟1, 王茜1 |
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(1.国防科技大学 航天与材料工程学院，湖南 长沙 410073;2.海军工程大学 船舶与动力学院，湖北 武汉 430033)
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| 摘要: |
| 在合成中间体二(4-叔丁基苯基)羟乙酮基础上，进一步合成了双(1,2-二(4-叔丁基苯基)-1,2-二硫代双烯)镍络合物(DYE-02)，利用核磁共振氢谱、红外光谱和元素分析等方法对中间体及DYE-02的结构进行了表征，并研究了DYE-02自身的光稳定性能及其对菁染料(Cy7)的光稳定作用。结果表明，与双(1,2-二苯基-1,2-二硫代双烯)镍络合物(DYE-01)相比，苯环上引入叔丁基后，DYE-02的最大近红外吸收波长在885nm,发生明显的红移,具备更好的自身光稳定性，并且能明显提高菁染料的光稳定性。 |
| 关键词: 二(4-叔丁基苯基)羟乙酮 硫代双烯镍络合物 近红外吸收 光稳定性 |
| DOI： |
| 投稿日期：2008-02-28 |
| 基金项目: |
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| Synthesis of New Bis(1,2-diaryl-1,2-ethylenedithiolato) Nickel Complex and its Photostability to Cyanine Dye |
| MEN Jinfeng1,2, CHENG Haifeng1, CHEN Zhaohui1, CHU Zengyong1, ZHENG Wenwei1, WANG Qian1 |
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(1.College of Aerospace and Materials Engineering, National Univ. of Defense Technology, Changsha 410073, China;2.College of Naval Architecture and Power, Navy Univ. of Engineering, Wuhan 430033, China)
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| Abstract: |
| Bis(4-tertbutylphenyl)hydroxyketone and bis(1,2-di(4-tertbutylphenyl)-1,2-ethylenedithiolato) nickel complex (DYE-02) were synthesized and characterized by elemental analysis, 1H NMR and infrared spectra. The photostabilization of DYE-02 and its photostability to cyanine dye(Cy7) were studied. The results show that DYE-02 has a bathochromic shift absorbing in near infrared at 855nm. In addition, DYE-02 has better self photostabilization and better photostability to Cy7 than bis(1,2-diphenyl-1,2-ethylene dithiolato) nickel complex (DYE-01). |
| Keywords: bis(4-tertbutylphenyl)hydroxyketone bis(1,2-diaryl-1,2-ethylenedithiolato) nickel complex near infrared absorbing photostability |
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